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IN THIS CHAPTER Summary: A solution is a homogeneous mixture composed of a solvent and one or more solutes The solvent is the substance that acts as the dissolving medium and is normally present in the greatest amount Commonly the solvent is a liquid, but it doesn t have to be Our atmosphere is a solution with nitrogen as the solvent; it is the gas present in the largest amount (79%) Many times you will be dealing with a solution in which water is the solvent, an aqueous solution The solute is the substance that the solvent dissolves and is normally present in the smaller amount You may have more than one solute in a solution For example, if you dissolved table salt (sodium chloride) and table sugar (sucrose) in water, you would have one solvent (water) and two solutes (sodium chloride and sucrose) Some substances will dissolve in a particular solvent and others will not There is a general rule in chemistry that states that like dissolves like This general statement may serve as an answer in the multiple-choice questions, but does not serve as an explanation in the free-response questions This simply means that polar substances (salts, alcohols, etc) will dissolve in polar solvents such as water, and nonpolar solutes, such as iodine, will dissolve in nonpolar solvents such as carbon tetrachloride The solubility of a particular solute is normally expressed in terms of grams solute per 100 mL of solvent (g/mL) at a specified temperature The temperature must be specified because the solubility of a particular substance will vary with the temperature Normally, the solubility of solids dissolving in liquids increases with increasing temperature, while the reverse is true for gases dissolving in liquids A solution in which one has dissolved the maximum amount of solute per given amount of solvent at a given temperature is called a saturated solution 179.

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1 atm The result is a curve the first part of which is like that in Fig 1423 When monolayer coverage is nearly complete, multilayer adsorption begins, and the curve changes direction, with n increasing ever more rapidly with pressure Finally, as the pressure approaches 1 atm, the vapor pressure of the N2adsorbate, the curve becomes nearly vertical because of condensation in the pores of the adsorbent The problem is to identify the point on the curve that represents full monolayer coverage The usual procedure is to fit the Brunauer/Emmett/Teller (BET) equation, a 2-parameter extension of the Langmuir isotherm to multilayer adsorption, to the n vs P data From this, one can determine a value for m27 Once m is known, multiplication by Avogadro's number and by the area occupied by one adsorbed N2molecule (162 A2)yields the surface area The method has its uncertainties, particularly for molecular sieves where the pores may contain unadsorbed molecules Nevertheless, it is a useful and widely used tool for characterizing and comparing adsorption capacities

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